| 14/05/2022 |  |
Arminia BielefeldArminia Bielefeld | 1 | x | 1 | RB LeipzigLeipzig |  |
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| 14/05/2022 |  |
Borussia DortmundDortmund | 2 | x | 1 | Hertha BerlinHertha |  |
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| 14/05/2022 |  |
Bayer LeverkusenBayer Leverkusen | 2 | x | 1 | SC FreiburgFreiburg |  |
||
| 14/05/2022 |  |
MainzMainz | 2 | x | 2 | Eintracht FrankfurtFrankfurt |  |
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| 14/05/2022 |  |
Borussia MönchengladbachGladbach | 5 | x | 1 | TSG HoffenheimHoffenheim |  |
||
| 14/05/2022 |  |
VfB StuttgartStuttgart | 2 | x | 1 | FC KölnKöln |  |
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| 14/05/2022 |  |
VfL WolfsburgWolfsburg | 2 | x | 2 | Bayern MünchenBayern |  |