| 22/10/2022 |  |
Rayo VallecanoRayo Vallecano | 5 | x | 1 | CádizCádiz |  |
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| 22/10/2022 |  |
1 | x | 0 | Real SociedadReal Sociedad |  |
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| 22/10/2022 |  |
ValenciaValencia | 1 | x | 2 | MallorcaMallorca |  |
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| 22/10/2022 |  |
Real MadridReal Madrid | 3 | x | 1 | SevillaSevilla |  |
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| 23/10/2022 |  |
EspanyolEspanyol | 2 | x | 2 | ElcheElche |  |
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| 23/10/2022 |  |
Real BetisReal Betis | 1 | x | 2 | Atlético MadridAtlético Madrid |  |
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| 23/10/2022 | |
1 | x | 1 | OsasunaOsasuna |  |
|||
| 23/10/2022 |  |
VillarrealVillarreal | 2 | x | 1 | |
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| 23/10/2022 |  |
BarcelonaBarcelona | 4 | x | 0 | |
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| 24/10/2022 |  |
Celta VigoCelta Vigo | 1 | x | 1 | GetafeGetafe |  |